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By T E. Thorpe

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Care is essential to the life of the pan which depends on the mixture of iron used in the casting, on the strength of the vitriol used, on the design of the pan setting, and, of course, also on the carefulness of the men working the charges. With attention to these points salt- cake-pans will last while the furnaces produce up to 4000 tons of salt-cake. Whether the roaster be an open or a blind one, the work in salt-cake making, as far as the pan is concerned, is almost entirely the same. Only the size of the batches differs in the two With open roasters, which admit of finishing a batch once an hour, or even oftener, batches are made of 6 or 8, or at most 10, cwt.

It is made technically Sodium ; Three sulphites of sodium the normal sulphite, the bisul- sulphites. of sodium chloride and ammonium sulphite. If a cold, saturated solution of the heptahydrated salt be heated, a crystalline precipitate of the anhydrous salt is formed. The salt is unalterable in air and dissolves readily in Avater ; by evaporation of the solution white, monoclinic crystals of the heptahydrate are obtained. These have a sharp taste, effloresce on exposure to air, and dissolve fairly easily in Avater, yielding a solution Avhich reacts alkaline.

Methyl alcohol at ordinary temperatures, and If sodium is also very soluble in acetone. Avith 19 dioxide Na 2 C0 8 +2S0 2 -fH 2 0=2NaHS0 3 +C0 2 2NaHS0 3 +Na 2 C0 3 =2Na 2 S0 3 +CO 2 . Sodium bisulphite NaHS0 3 is produced by saturating a solution of sodium carbonate Avith sulphur dioxide. It forms a Avhite pOAvder, smelling of sulphur dioxide, is only sparingly soluble in water, and is precipitated from its aqueous solution by alcohol. On heating, it decomposes, evolving sulphur and sulphur dioxide and leaving a residue of sulphate.

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A Dictionary of Applied Chemistry by T E. Thorpe


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