By J R Hanson; R B Boar; Royal Society of Chemistry.; et al
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Additional resources for A review of the literature published between September 1979 and August 1980
H. , 1980, 21, 1921. Sesquiterpenoids 41 CH20H GlucO HO OH OH (271) (270) H02C* OH (272) * R (273) R (2741 R = = H OH \ OH OH (276) R (277) R (278) R = = = C1 OGluc OAllosyl (279) R' (280) R' (281) R' = = = CH20H, R2 = Me Me,R2 = CH20H C02H, R2 = Me A full report on the synthesis of dihydrofomannosin acetate (284) has been p ~ b l i s h e d . ' In ~ ~a follow-up paper on the biosynthesis of fomannosin (287), Cane and N a ~ h b e r have l ~ ~ used a number of incorporation experiments (particularly with [5,5-2H2]mevalonate)to show that fomannosin cannot be formed by the sequence (285) + (287) as shown in Scheme 28, since no deuterium incorporation could be detected at C-12.
Yrir. Soedin. (Engl. ), 1979, 572. I. Bryson, J. S. Roberts, and A. , 1980, 21, 201. H. Shirahama, E. Osawa, and T. Matsumoto, J. Am. Chem. ,1980, 102,3208. "~ information can be extrapolated to the retention of configuration at the relevant centres of farnesyl pyrophosphate (269). (265) R' = CHO, R2 = COzH, R3 = H (266) R' = C H 0 , R 2 = C02H,R3 = AC (267) R' = COZH,R2 = CHZOH, R3 = Ac (268) (269) A further investigation of fern species has resulted in the identification of additional pterosin and ptersoide derivatives, viz.
A review of the literature published between September 1979 and August 1980 by J R Hanson; R B Boar; Royal Society of Chemistry.; et al